๐”– Bobbio Scriptorium
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Demonstration of a heterolytic mechanism for the reaction of triphenyl tin hydride

โœ Scribed by A. E. Borisov; A. N. Abramova; Z. N. Parnes

Book ID
112420266
Publisher
Springer
Year
1964
Tongue
English
Weight
199 KB
Volume
13
Category
Article
ISSN
1573-9171

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Rate constants for reaction of a fluorou
Rate constants for reaction of a fluorous tin hydride reagent with primary alkyl radicals
โœ John H. Horner; Felix N. Martinez; Martin Newcomb; Dennis P. Curran ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 224 KB

Rate constants for 6-exo cyclization of the 7,7-diphenyl-6-heptenyl radical (3) in benzotrifluoride (BTF, PhCF3) were determined by laser flash photolysis, and radical clock 3 was used in competition kinetic studies for determination of rate constants of reactions of the fluorous tin hydride reagent