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Demanding and structure-insensitive nature of ethane-deuterium exchange reaction

✍ Scribed by L. Guczi; J. Sárkány


Book ID
113176507
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
145 KB
Volume
68
Category
Article
ISSN
0021-9517

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Hydrogen-deuterium isotope effects for t
✍ P.J. Smith; S.K. Tsui 📂 Article 📅 1973 🏛 Elsevier Science 🌐 French ⚖ 204 KB

In a recent publication2 the mechanism of the reaction of i-arylethyltrimethylammonium ions with ethoxide ion in ethanol at 70° was shown to be E2. The transition state for this process involved extensive proton transfer to base as exhibited by the observed trend in hydrogendeuterium isotope effects