✍ Scribed by W. Baumann
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Gas-phase noncovalently bound complexes are probed by hydrogen/deuterium exchange. The complexes, composed of a protonated amino acid and a monosaccharide, are investigated to observe the effects of complexation on the rates of exchange. Rate constants are determined and compared for complexed and u
## Abstract Conventional thermal and microwave conditions were compared for hydrogen–deuterium (H/D) exchange reactions of aminobenzoic acids catalysed by NaBD~4~‐activated Pd/C or RhCl~3~ with D~2~O as the deuterium source. We also investigated different NaBD~4~‐activated metal catalysts (includin
Gas-phase hydrogen-deuterium (H/D) exchange reactions involving four isomeric cyclopropane derivatives were investigated under chemical ionization (CI) conditions, using D(2)O and CD(3)OD as reagent gases. There are abundant ions at [M + 1](+), [M + 2](+) and [M + 3](+) in the D(2)O and CD(3)OD posi
The gas-phase H-D exchange reactions of protonated amino acids and small peptides with ND, have been studied for reactions occurring in the quadruple collision cell of a hybrid BEqQ mass spectrometer (B = magnetic sector, E = electric sector, q = quadrupole collision cell, Q = quadrupole mass analyz