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Deltacyclene formation catalysed by cationic Co(II) complexes

✍ Scribed by P. Binger; S. Albus


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
196 KB
Volume
493
Category
Article
ISSN
0022-328X

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Asymmetric cyclopropanation catalysed by
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Several clays, exchanged with cationic bis(oxazoline)-Cu u complexes, have been tested as catalysts in the benchmark cyclopropanation reaction of styrene with ethyl diazoacetate. Either the catalytic activity or the enantioselectivity are improved with regard to the same complexes when used in homog