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Regio- and Stereoselective Intermolecular Hydroalkoxylation of Alkynes Catalysed by Cationic Gold(I) Complexes

✍ Scribed by Avelino Corma; Violeta R. Ruiz; Antonio Leyva-Pérez; María J. Sabater


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
360 KB
Volume
352
Category
Article
ISSN
1615-4150

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Reaction of the cationic binuclear gold(I) complex [(Ph 3 PAu) 2 Cl]BF 4 with w-alkynylfurans furnished phenols as the major product and anellated furans as the side-products. The analogous trimesitylphosphane complex [(Mes 3 PAu) 2 Cl]BF 4 selectively afforded only the phenols. The latter catalyst