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Delocalization of Methyl Groups Protons or Deuterons in Molecular Compounds

✍ Scribed by J. Meinnel; A. Cousson; F. Boudjada; M. Plazanet; M. Mani


Book ID
110216991
Publisher
Springer US
Year
2001
Tongue
English
Weight
307 KB
Volume
122
Category
Article
ISSN
0022-2291

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Molecular dynamics of 17Ξ±- and 21-hydrox
✍ A. Szyczewski; K. HoΕ‚derna-Natkaniec πŸ“‚ Article πŸ“… 2005 πŸ› Elsevier Science 🌐 English βš– 233 KB

For the two steroid compounds 17aOH-progesterone and 21OH-progesterone, the activation energies of reorientations of the methyl groups have been determined. Their values together with results of the quantum chemical calculations permitted establishment of the sequence of the onset of the methyl grou