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Molecular structure and dynamic solution behavior of the bridging 1,3-dimetallaallyl ligand in (Me3SiCH2)4W2(.mu.-CSiMe3)(.mu.-C3R2SiMe3) compounds (R = hydrogen, methyl, or phenyl) formed by insertion of alkynes into a bridging (.mu.2) ligand

✍ Scribed by Chisholm, Malcolm H.; Heppert, Joseph A.; Huffman, John C.

Book ID: 126241881
Publisher: American Chemical Society
Year: 1984
Tongue: English
Weight: 418 KB
Volume: 106
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00316a075

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📜 SIMILAR VOLUMES

Formation of .eta.1-iminoacyl compounds

Formation of .eta.1-iminoacyl compounds by insertion of isonitriles into pentamethylcyclopentadienyl-tetramethylfulvene compounds of titanium and zirconium. Intramolecular C-H activation of a pentamethylcyclopentadienyl group to give a tridentate ligand with two bridged cyclopentadienyl rings and a titanium-vinyl bond in the bridge. Molecular structure of [cyclic][.eta.5:.eta.1:.eta.5-C5Me4CH2C(NHXyl):CN(Xyl)CH2C5Me4]TiCl and [cyclic]Cp*[.eta.5:.eta.1-C5Me4CH2C(:NXyl)C(:NXyl)]ZrCl (Xyl=2,6-Me2C6H3)

✍ Fandos, Rosa.; Meetsma, Auke.; Teuben, Jan H. 📂 Article 📅 1991 🏛 American Chemical Society 🌐 English ⚖ 916 KB