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Dehydromonocrotaline, C16H21NO6: active metabolite of the pyrrolizidine alkaloid monocrotaline

✍ Scribed by Mackay, M. F. ;Sadek, M. ;Culvenor, C. C. J. ;Smith, L. W.

Book ID
114502013
Publisher
International Union of Crystallography
Year
1984
Tongue
English
Weight
437 KB
Volume
40
Category
Article
ISSN
0108-2701

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Alkylation of nucleosides by dehydromono
Alkylation of nucleosides by dehydromonocrotaline, the putative toxic metabolite of the carcinogenic pyrrolizidine alkaloid monocrotaline
✍ Haruki Niwa; Takeshi Ogawa; Osamu Okamoto; Kiyoyuki Yamada πŸ“‚ Article πŸ“… 1991 πŸ› Elsevier Science 🌐 French βš– 265 KB

## Reaction of dehydmmonocrotaline (3), the putative toxic metabolite of the carcinogenic pyrrolizidinc alkaloid monoerotahne (Z), with various nucleosides proceeded mostly at the C-9" position of 3 to give several nitrogen atom-alkylated nucleosides including N-7 alkylated 2'deoxyguanosine 14. P