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Dehydrogenation of steroidal ketones using benzeneseleninic anhydride

✍ Scribed by Barton, Derek H. R.; Lester, David J.; Ley, Steven V.

Book ID
120734241
Publisher
The Royal Society of Chemistry
Year
1978
Tongue
English
Weight
131 KB
Volume
3
Category
Article
ISSN
0022-4936

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πŸ“œ SIMILAR VOLUMES

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## Abstract Treatment of chaparrinone triacetate with benzeneseleninic anhydride afforded in addition to the Ξ”^14,15^‐dehydro compound two products arising from angular hydroxylation at C(5). The mechanism of this reaction is discussed. The corresponding deacetylated compounds do not display signif

Preparation of aldehydes and ketones by
Preparation of aldehydes and ketones by oxidation of benzylic hydrocarbons with benzeneseleninic anhydride
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Benzeneseleninic anhydride is a mild oxidant for the conversion of benzylic hydrocarbons into aldehydes or ketones. Although oxidation of aromatic side chains can be achieved by a variety of methods, there is still a need for new reagents which will effect this transformation. Recently benzenesele