Dehydrogenation of methanol to methyl formate over CuO−SiO2 gel catalyst
✍ Scribed by Zhang, Rong ;Sun, Yu-han ;Peng, Shao-yi
- Publisher
- Springer
- Year
- 1999
- Tongue
- English
- Weight
- 325 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0133-1736
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Dehydrogenation of methanol to methyl formate was carried out using copper-exchanged clays as catalysts. Methanol was selectively dehydrogenated to methyl formate on copper-exchanged laponite and fluoro tetrasilicic mica. In contrast, copper-exchanged montmorillonite and saponite only catalyzed the
FTIR spectra are reported for methanol and methyl formate on silica-supporled potassium. potassium-promoted reduced copper/silica, and a potassium-promoled copper/silica catalyst which had been reoxidised by nitrous oxide. Adsorption of methanol on potassium/silica resulted in the formation of metho