The reaction of [Ir(m-Cl)(COD)] 2 with various fluorous derivatives of triphenylphosphane containing a para-, meta-, or ortho-(1H,1H-perfluoroalkoxy)-substituted fluorous phosphane P(C 6 H 4 -ORf) 3 (Rf CH 2 C 7 F 15 , CH 2 CH 2 CH 2 C 8 F 17 ) and CO (1 atm) gives the corresponding trans-[Ir(m-Cl)(
✦ LIBER ✦
Dehydrocoupling of Phosphanes Catalyzed by a Rhodium(I) Complex
✍ Scribed by Volker P. W. Böhm; Maurice Brookhart
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 77 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0044-8249
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## Abstract A novel chelated ferrocene‐based planar chiral N‐heterocyclic carbene‐Rh(I) complex was synthesized by a simple method. It was applied to the asymmetric transfer hydrogenation of prochiral ketones. Enantioselectivities of up to 67% ee were observed. Copyright © 2009 John Wiley & Sons, L