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Degradation of dinitrated-poly(n-vinylcarbazole) by thermogravimetry

✍ Scribed by M.C. Gonzalez; F. Zamora

Publisher: Elsevier Science
Year: 1990
Tongue: English
Weight: 334 KB
Volume: 26
Category: Article
ISSN: 0014-3057
DOI: 10.1016/0014-3057(90)90046-7

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✦ Synopsis

The techniques of isothermal and dynamic thermogravimetry have been used to study the degradation of six nitrated homodisperse fractions of poly(N-vinylcarbazole). The effects of nitrogen content and molecular weight of the samples on kinetic parameters are reported. Increasing the heating rate or using higher isothermal temperatures causes a sudden mass-loss and an increasing sample temperature was observed. An induction period in which -NO 2 scission took place may be the cause of this sudden mass-loss.

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