## Abstract The eight spin NMR spectrum (400 MHz) of bicyclopropylidene oriented in a nematic phase has been analysed. The absolute signs and values of ^5^__J__(HH) longβrange spinβspin coupling constants have been determined for the first time for this molecule. The ratios of interatomic Hο£ΏH dista
Deformation of methylenecyclopropane in solution: NMR study in the nematic phase at 240 and 400 MHz
β Scribed by J. Courtieu; Y. Gounelle; J. Jullien; G. Balavoine; M. Fan
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 260 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0749-1581
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β¦ Synopsis
Abstract
The NMR spectrum of methylenecyclopropane oriented in two nematic phases has been measured at 240 and 400 MHz. Ratios of the protonβproton distances have been obtained. These values are compared with those deduced from the structure of the molecule in the gaseous state; they suggest an increase of the ethylenic magnified image angle in the nematic phase.
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