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Dediazoniations of Arenediazonium Ions in Homogeneous Solutions. Part XV. Products of dediazoniation of p-chlorobenzenediazonium tetrafluoroborate in weakly alkaline aqueous solutions

✍ Scribed by Jacques Besse; Wolfgang Schwarz; Heinrich Zollinger

Publisher
John Wiley and Sons
Year
1981
Tongue
German
Weight
523 KB
Volume
64
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The products of decomposition of solutions of p‐chlorobenzenediazonium tetrafluoroborate in aqueous buffer solutions (pH 9.0–10.3; ionic strength 0.1–0.5) at 20.0° have been analyzed quantitatively. Up to eleven low molecular weight compounds could be identified besides the major product, the complex polymeric diazo tar. The distribution of products is influenced by trace amounts of oxygen as well as by p‐chlorophenol and the radical trapping reagent iodoacetic acid. Mechanisms of formation of the products are discussed.

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