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Dediazoniations of Arenediazonium Ions in Homogeneous Solution. Part XIV. 15N-CIDNP. Investigation of the reactions of diazonium ions in weakly alkaline aqueous solutions

✍ Scribed by Eberhard-Ludwig Dreher; Paul Niederer; Anton Ricker; Wolfgang Schwarz; Heinrich Zollinger

Publisher
John Wiley and Sons
Year
1981
Tongue
German
Weight
869 KB
Volume
64
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

^15^N‐CIDNP. spectra recorded during the reaction of diazonium cations with OH^−^ in weakly alkaline aqueous solutions show that the dediazoniation is at least partially homolytic. The polarizations observed for the diazonium and trans‐diazotate ions can be explained by reaction proceeding via a cage involving diazenyl and diazotate radicals using Kaptein's rules and simple intensity considerations.

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