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Decompositions of Di-t-Alkyl Peroxides. I. Kinetics

โœ Scribed by Raley, John H.; Rust, Frederick F.; Vaughan, William E.

Book ID
126240574
Publisher
American Chemical Society
Year
1948
Tongue
English
Weight
620 KB
Volume
70
Category
Article
ISSN
0002-7863

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The thermal decomposition of perfluoro-di-t-butyl peroxide has been studied for the first time. The reaction was carried out in the gas phase between 5 and 600 torr in the 10&149"C temperature region. The products consisted solely of CzFa and CFJCOCF,. The decomposition wits found to be first order