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Decomposition of unsaturated fatty acid hydroperoxides by hemoglobin: Structures of major products of 13L-hydroperoxy-9,11-octadecadienoic acid

โœ Scribed by Mats Hamberg

Book ID
112770961
Publisher
Springer-Verlag
Year
1975
Tongue
English
Weight
427 KB
Volume
10
Category
Article
ISSN
0024-4201

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A solution of methyl 13(S)-hydroperoxy-9(Z),ll(E)-octadecadienoate (13-HPOD)in methanol was irradiated under anaerobic conditions at 15ยฐC with light at wavelengths greater than 230 nm. After 2 h the 13-HPOD was completely degraded and four major products were formed. Three of them were identified as

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in the presence of oxygen, UV-irradiation of a solution of methyl 13(S)-hydroperoxy-9(Z),l I(E)octadecadienoate (13-HPOD) in methanol yields stereoisomers of methyl 9,13-dihydroxy-10methoxy-1 l(E)-octadecenoate and methyl 9,13-dihydroxy-12-methoxy-10(E)-octadecenoate as major products. The reaction