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Decomposition of the metastable SF4− ion

✍ Scribed by P.W. Harland; J.C.J. Thynne

Book ID
107768563
Publisher
Elsevier Science
Year
1971
Weight
106 KB
Volume
7
Category
Article
ISSN
0020-1650

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Rearrangements in metastable ion decompo
Rearrangements in metastable ion decompositions of protonated propylamines
✍ Henri E. Audier; Thomas Hellman Morton 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 715 KB

Decomposition of nPrNH,+ to NH,+ does not occur via vicinal elimination. Hydrogen transfer takes place from all positions of the alkyl chain. Intermediacy of either an ion-neutral complex, (iPr+ NH,], or rearrangement to iPrNH,+ is required. SCF calculations were used to probe the potential energy s