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Decomposition of the 1,3-butadiene radical cation on the microsecond to picosecond time scale

✍ Scribed by Russell, D. H.; Gross, M. L.; Van der Greef, J.; Nibbering, N. M. M.


Book ID
126978448
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
643 KB
Volume
101
Category
Article
ISSN
0002-7863

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## Abstract Polybutadiene‐ol was synthesized by solution radical polymerization of 1,3‐butadiene in the presence of hydrogen peroxide as initiator and 2‐propanol as solvent. The ratio of initiator to monomer molar concentration, [I~0~]/[M~0~], was varied while temperature, reaction time and the typ