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Cope and 1,3-allylic rearrangements and ring closure of the 1,5-hexadiene radical cation prior to decomposition in the gas phase

โœ Scribed by Wolkoff, P.; Holmes, J. L.


Book ID
127178517
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
419 KB
Volume
47
Category
Article
ISSN
0022-3263

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1,3,5-Cycloheptatriene (1) and various 7-alkyl-1,3,5-cycloheptatrienes (3, 6, 9, 13, and 16-19) were subjected to gas-phase protonation under and conditions and the MIKE spectra of their [ M + H ] ' ions CI(CH 4 ) CI(iC 4 H 10 ) were measured. Loss of from the parent ion [ 1 + H ] ' and almost exclu