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Decomposition of N-nitrosamines, and concomitant release of nitric oxide by Fenton reagent under physiological conditions

โœ Scribed by K. Hiramoto; Y. Ryuno; K. Kikugawa


Book ID
117766995
Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
179 KB
Volume
520
Category
Article
ISSN
1383-5718

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Selective functionalisation of hydrocarb
โœ Francesco Minisci; Francesco Recupero; Cristian Gambarotti; Carlo Punta; Roberto ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 145 KB

Alkylbenzenes are selectively functionalised to the corresponding acetates by nitric aerobic oxidation catalysed by N-hydroxyphthalimide and iodine. With cyclohexane the oxidation leads to a mixture of cyclohexyl acetate and trans-2-iodocyclohexyl acetate. The mechanism is discussed.