Au extension of the usual system-size expansion method is given to study the relaxation and fluctuation from unstable and metastable states. The short-time and the long-time behavior of the moments y(t) and M,(t) and of the distribution function P(x, t) of a macrosco0ic variable x are investigated b
Decay of metastable and unstable states: Mechanisms, concepts and open problems
โ Scribed by K. Binder
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 466 KB
- Volume
- 140
- Category
- Article
- ISSN
- 0378-4371
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โฆ Synopsis
The decay of metastable states is initiated by a nucleation process in which a free energy barrier is overcome, while in unstable states fluctuations can grow unaffected by such a barrier. The first part of this review considers the significance of the spinodal line separating the metastable and unstable regime. A Ginzburg criterion for the validity of the spinodal line, as well as for the mean-field theory of nucleation and the linear theory of spinodal decomposition will be discussed. Evidence from simulations and experiments will be mentioned.
The second part considers the scaring behavior of the structure function (and droplet or domain size distribution, etc.) in the late stages of the decay: do we understand on which factors the associated exponents depend? Is there a universality as in critical phenomena?
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