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Decarboxylation of 6-Nitrobenzisoxazole-3-carboxylate in Mixed Micelles of Zwitterionic and Positively Charged Surfactants

โœ Scribed by Maximiano, Flavio A.; Chaimovich, Hernan; Cuccovia, Iolanda M.


Book ID
126126112
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
110 KB
Volume
22
Category
Article
ISSN
0743-7463

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The effects of ethanol on the critical micellar concentration (cmc) and the rates of decarboxylation of 6-nitrobenzisoxazole-3-carboxylate (6-NBIC) have been investigated in aqueous cationic surfactants of the cetyltrialkylammonium family with bromide [CT(R)ABr], chloride [CT(R)ACl], and nitrate [CT

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## NOTE Decarboxylation of 6-Nitrobenzisoxazole-3-Carboxylate Ion in Dichloromethane: The Effects of Surfactant Structure ation of 1 is relatively simple; with or without added water bulky groups at the ammonium ion center increase catalysis, probably by making it The spontaneous decarboxylation