## NOTE Decarboxylation of 6-Nitrobenzisoxazole-3-Carboxylate Ion in Dichloromethane: The Effects of Surfactant Structure ation of 1 is relatively simple; with or without added water bulky groups at the ammonium ion center increase catalysis, probably by making it The spontaneous decarboxylation
Decarboxylation of 6-nitrobenzisoxazole-3-carboxylate ion in dichloromethane: The possible role of reverse micelles
โ Scribed by Raimondo Germani; Pier Paolo Ponti; Nicoletta Spreti; Gianfranco Savelli; Antonio Cipiani; Giorgio Cerichelli; Clifford A Bunton; Victoria Si
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 584 KB
- Volume
- 138
- Category
- Article
- ISSN
- 0021-9797
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๐ SIMILAR VOLUMES
The effects of ethanol on the critical micellar concentration (cmc) and the rates of decarboxylation of 6-nitrobenzisoxazole-3-carboxylate (6-NBIC) have been investigated in aqueous cationic surfactants of the cetyltrialkylammonium family with bromide [CT(R)ABr], chloride [CT(R)ACl], and nitrate [CT
## Abstract Reverse micellar systems are of interest as reaction media because they are powerful models for biological compartmentalization, enzymatic catalysis and separation of biomolecules. Solutions of ionic surfactants in apolar solvents may contain reverse micelles, but they may also contain