Steric effects in bicyclic ring systems.
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Satya P. Jindal; Sangeeta S. Sohoni; Thomas T. Tidwell
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Article
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1971
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Elsevier Science
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French
⚖ 196 KB
It has been found that rates of base-catalyzed deuterium exchange of bicyclic ketones2'3'4 and bicyclic nitriles are a sensitive probe for the chemical consequenc-e~ of structural variation. Results reported herein for exchange of bicyclo[Z.l..l]hexan-Z-one (2) and bicyclo[Z.Z.Z]octan-Z-one (c). whe