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Decarboxylation and Deuterium Exchange in Some Azabicyclic Ketone Systems 1

✍ Scribed by House, Herbert O.; Müller, Hanspeter C.


Book ID
126896845
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
469 KB
Volume
27
Category
Article
ISSN
0022-3263

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It has been found that rates of base-catalyzed deuterium exchange of bicyclic ketones2'3'4 and bicyclic nitriles are a sensitive probe for the chemical consequenc-e~ of structural variation. Results reported herein for exchange of bicyclo[Z.l..l]hexan-Z-one (2) and bicyclo[Z.Z.Z]octan-Z-one (c). whe