Steric effects in bicyclic ring systems. III. Evaluation of torsional strain in base-catalyzed deuterium exchange of ketones and hydroboration of olefins

Steric effects in bicyclic ring systems.

Steric effects in bicyclic ring systems. II. Angle strain and non-bonding repulsion in base-catalyzed deuterium exchange of bicyclic ketones

✍ Satya P. Jindal; Sangeeta S. Sohoni; Thomas T. Tidwell 📂 Article 📅 1971 🏛 Elsevier Science 🌐 French ⚖ 196 KB

It has been found that rates of base-catalyzed deuterium exchange of bicyclic ketones2'3'4 and bicyclic nitriles are a sensitive probe for the chemical consequenc-e~ of structural variation. Results reported herein for exchange of bicyclo[Z.l..l]hexan-Z-one (2) and bicyclo[Z.Z.Z]octan-Z-one (c). whe