✦ LIBER ✦

Decarbonylative Radical Cyclization of α-Amino Selenoesters upon Electrophilic Alkenes. A General Method for the 6-Azabicyclo[3.2.1]octane Synthesis

✍ Scribed by Quirante, Josefina; Vila, Xavier; Escolano, Carmen; Bonjoch, Josep

Book ID: 121370031
Publisher: American Chemical Society
Year: 2002
Tongue: English
Weight: 83 KB
Volume: 67
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo0163849

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

ChemInform Abstract: Decarbonylative Rad

ChemInform Abstract: Decarbonylative Radical Cyclization of α-Amino Selenoesters upon Electrophilic Alkenes. A General Method for the 6-Azabicyclo[3.2.1]octane Synthesis.

✍ Josefina Quirante; Xavier Vila; Carmen Escolano; Josep Bonjoch 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB 👁 1 views

ChemInform Abstract: A New Method to Gen

ChemInform Abstract: A New Method to Generate α-Aminoalkyl Radicals: Treatment of Methyl α-Amino Selenoesters with Hydride Reagents. Synthesis of 6-Azabicyclo(3.2.1)octanes by Radical Cyclization.

✍ J. QUIRANTE; C. ESCOLANO; J. BONJOCH 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

A New Method to Generate α-Aminoalkyl Radicals: Treatment of Methyl α-Amino Selenoesters with Hydride Reagents. Synthesis of 6-Azabicyclo(3.2.1)octanes by Radical Cyclization. -α-Amino selenoesters on heating with Bu3SnH or Tms3SiH undergo decarbonylation to afford intermediate α-aminoalkyl radical