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Decarbonylation of aliphatic α,β-unsaturated aldehydes using the Wilkinson complex

✍ Scribed by N. Ya. Grigor'eva; O. A. Pinsker; A. V. Semenovskii

Book ID
112444395
Publisher
Springer
Year
1983
Tongue
English
Weight
148 KB
Volume
32
Category
Article
ISSN
1573-9171

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Enantioselective addition of oxindoles t
Enantioselective addition of oxindoles to aliphatic α,β-unsaturated aldehydes
✍ Natalia Bravo; Ignasi Mon; Xavier Companyó; Andrea-Nekane Alba; Albert Moyano; R 📂 Article 📅 2009 🏛 Elsevier Science 🌐 French ⚖ 256 KB

A highly enantioselective organocatalytic oxindole addition to a,b-unsaturated aldehydes is reported. The reaction is catalyzed by simple and commercially available chiral secondary amines, affording the corresponding adducts with good yields and with moderate diastereoselectivities.