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Decarbalkoxylation of isohexylmalonates

โœ Scribed by Markgraf, J. Hodge; Ibsen, Mark S.; Kinney, John B.; Kuper, Jerry W.; Lurie, Jonathan B.; Marrs, David R.; McCarthy, Cheryl A.; Pile, Judith M.; Pritchard, Timothy J.

Book ID
126459223
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
284 KB
Volume
42
Category
Article
ISSN
0022-3263

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Recently Krapcho and Lovey have reported that germinal diesters, B-keto esters and a-cyano esters undergo decarbalkoxylatlons when heated with sodium chloride In wet dimethyl eulfoxide at temperatures of 140-185' (1). We now wish to report further experiments addressed to the question of whether add