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Decapitation of dihydroporphyrazinediol derivatives: synthesis and X-ray structure of a novel seco-porphyrazine

✍ Scribed by Nie, Hanlin; Stern, Charlotte L.; Hoffman, Brian M.; Barrett, Anthony G. M.


Book ID
121321500
Publisher
Royal Society of Chemistry
Year
1999
Tongue
English
Weight
140 KB
Volume
8
Category
Article
ISSN
1359-7345

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Synthesis and X-ray structure of a novel
✍ Martin R. Bryce; Alexander K. Lay; Andrei S. Batsanov; Judith A. K. Howard πŸ“‚ Article πŸ“… 1999 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 171 KB

## Abstract Photolysis of 1,2‐dithiole‐3‐thione derivative 1 results in the formation of the 1,2,4‐trithiolane derivative 2, the structure of which was established by single crystal X‐ray analysis. Interesting bond delocalisation is observed in the molecular structure. A mechanism involving dimeris