Using laser-induced fluorescence of ozone (to measure the rate of disappearance of Os?) and NOz titration (to determine 0 atom concentrations), we have determined bimolecular rate constants for the deactivation by 0(3? atoms) of ozone in excited stretching and bending modes. These experiments do not
Deactivation of vibrationally excited N2 by H2O
โ Scribed by J. Nagel; D. Rogovin
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 347 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The W exchange rate for thr Nz-1110 system is determined usmg a hard-core repuist\c patcntial. It is found that the' rapid drzxriration rate zmses from near-resonant VR exchanges in\ol;ing non-dipole ch;~nges in the rot.ttionaI <tdteS I'urIhermore, a chssicai-path approximation is used and the resultins rate found to be crttica& dependent on tilt pa111 chasm.
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