The laser induced fluorescence method has been used to measure the rate of deactivation of HF(u = 1) by F, 0, and H atoms at 300Β°K. The rate for F-atoms was found to be kF\_HF = (0.9 f 0.2) X lo4 set-' torr-', for Oatoms Lo\_m = (1.0 f 0.2) X lo5 set-' torr-', and for Hatoms, an upper limit to the r
Deactivation of vibrationally excited hydrogen fluoride (v=2 and v=1) by atomic fluorine
β Scribed by Jay A. Blauer; Wayne C. Solomon
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- English
- Weight
- 241 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0538-8066
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β¦ Synopsis
Abstract
Measurements have been made which provide information concerning the rate of energy transfer between vibrationally excited HF and atomic fluorine. It was found that HF (v = 1) deactivates about seven times slower than was determined in previous experiments. The deactivation rate constant for HF (v = 2) is about six times larger than for HF (v = 1).
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## Rate constants for the deacrivarion of N,(u= 1) by n-H, and by PHI between 300 and 80 K have ken measured using laser fluorescence from CO(u= 1). There is no n-HZ/p-Hz difference. N,(v=l) is deactivated about 3 times more slowly than is CO(u = 1). Comparison with results in liquid N, support t
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