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Das massenspektrometrische Verhalten quartärer Stickstoffverbindungen, III1)

✍ Scribed by Hesse, Manfred ;Schmid, Hans

Publisher
Wiley (John Wiley & Sons)
Year
1966
Weight
243 KB
Volume
696
Category
Article
ISSN
0074-4617

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Das unterschiedliche massenspektrometris
Das unterschiedliche massenspektrometrische Fragmentierungsverhalten von Lysinmethylester und dessen N,N′-Diacetylderivat. 27. Mitteilung über das massenspektrometrische Verhalten von Stickstoffverbindungen
✍ Felix Roessler; Manfred Hesse 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 German ⚖ 476 KB 👁 1 views

The base peak in the spectrum of lysine methyl ester is due to the fragment ion C ~H ~O N (m/e 84), for which the cyclic structure g (Scheme I ) is deduced. During its formation from the [M-COOCHsI-ion an equilibration of both nitrogen atoms takes place (ion c, Scheme I). The cyclic nature of ion m/