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Darzensreaction as a convenient method for the synthesis of α-chloroketones, α-chloroepoxides, and symmetrically substituted dioxines

✍ Scribed by V. A. Mamedov; I. A. Litvinov; O. N. Kataeva; I. Kh. Rizvanov; I. A. Nuretdinov


Book ID
104952470
Publisher
Springer Vienna
Year
1994
Tongue
English
Weight
431 KB
Volume
125
Category
Article
ISSN
0026-9247

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The first synthesis of diazoesters by direct diazotization of amino acid esters was reported by Curtius I,\*) around 1900. Although this method is well suited for the preparation of diazoacetic ester, 3) it is generally inapplicable to the syntheses of a-substituted-a-diazoesters (I),\*) because of