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Darstellung von dodecamethyl-1λ3,4λ3-diphospha-2,3,5,6,7,8-hexasilabicyclo[2.2.2]octan

✍ Scribed by K. Hassler

Book ID
103222332
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
251 KB
Volume
246
Category
Article
ISSN
0022-328X

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**White phosphorus reacts with 1,1,2,2‐tetramethyldislannane in the dark at 0°C to give the title compound**, which according to an X‐ray structure analysis has D~3~‐symmetry. The bicyclo[2.2.2]octane framework with P in the bridgehead position is constructed from three Sn~4~P~2~ six‐membered rings