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Decamethyl-1λ3,4λ3-diphospha-2,3,5,6,7-pentastannabicyclo[2.2.1]heptan, ein zinnreicher Bicyclus

✍ Scribed by Dr. Bernd Mathiasch; Prof. Dr. Martin Dräger

Publisher
John Wiley and Sons
Year
1978
Tongue
English
Weight
206 KB
Volume
90
Category
Article
ISSN
0044-8249

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**White phosphorus reacts with 1,1,2,2‐tetramethyldislannane in the dark at 0°C to give the title compound**, which according to an X‐ray structure analysis has D~3~‐symmetry. The bicyclo[2.2.2]octane framework with P in the bridgehead position is constructed from three Sn~4~P~2~ six‐membered rings