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d6 and d8 Metal Carbonyl Complexes of 7,7-Dimethoxy-5,6-dimethylidenebicyclo[2.2.1]hept-2-ene. Stereoselective Hydroformylation of an [Fe(CO)4(olefin)] Complex

โœ Scribed by Jacques Loset; Raymond Roulet


Publisher
John Wiley and Sons
Year
1985
Tongue
German
Weight
869 KB
Volume
68
Category
Article
ISSN
0018-019X

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โœฆ Synopsis


d6 and ds Metal Carbonyl Complexes of 7,7-Dimethoxy-5,6-dimethylidenebicyclo[2.2.l]hept-2-ene.


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The endocyclic double bond C(2),C( ) in 5,6-dimethylidene-7-oxabicyclo[2.2.1]hept-2-ene (1) can be coordinated selectively on its exo-face before complexation of the exocyclic s-cis-butadiene moiety. Irradiation of Ru,(CO),, or Os,(CO),, in the presence of 1 gave tetracarbonyl[(lR,2R,3S,4S)-2,3-~-(5

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