✦ LIBER ✦

D2-Symmetric Chiroporphyrins Derived from (1R)-cis-Hemicaronaldehydic Acid: Preparation and Spectral Characterization

✍ Scribed by Céline Pérollier; Marinella Mazzanti; Jean-Pierre Simonato; Franck Launay; René Ramasseul; Jean-Claude Marchon

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 358 KB
Volume: 2000
Category: Article
ISSN: 1434-193X
DOI: 10.1002/(sici)1099-0690(200002)2000:4<583::aid-ejoc583>3.0.co;2-e

No coin nor oath required. For personal study only.

✦ Synopsis

Esters, N,N-disubstituted amides, and a N-acylurea derived from the enantiopure industrial intermediate (1R)-cis-hemicaronaldehydic acid (or biocartol) are convenient synthons for the preparation of a series of chiroporphyrins by condensation with pyrrole. These chiral meso-tetracyclopropylporphyrins are obtained exclusively as the D 2 -symmetric α,β,α,β atropisomer, generally in low to moderate yields (2-20%), and in the urea case in excellent yield (60%). Hydro-

📜 SIMILAR VOLUMES

ChemInform Abstract: D2-Symmetric Chirop

ChemInform Abstract: D2-Symmetric Chiroporphyrins Derived from (1R)-cis-Hemicaronaldehydic Acid: Preparation and Spectral Characterization.

✍ Celine Perollier; Marinella Mazzanti; Jean-Pierre Simonato; Franck Launay; Rene 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 27 KB

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v