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ChemInform Abstract: D2-Symmetric Chiroporphyrins Derived from (1R)-cis-Hemicaronaldehydic Acid: Preparation and Spectral Characterization.

✍ Scribed by Celine Perollier; Marinella Mazzanti; Jean-Pierre Simonato; Franck Launay; Rene Ramasseul; Jean-Claude Marchon

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
31
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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D2-Symmetric Chiroporphyrins Derived fro
D2-Symmetric Chiroporphyrins Derived from (1R)-cis-Hemicaronaldehydic Acid: Preparation and Spectral Characterization
✍ Céline Pérollier; Marinella Mazzanti; Jean-Pierre Simonato; Franck Launay; René 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 358 KB 👁 1 views

Esters, N,N-disubstituted amides, and a N-acylurea derived from the enantiopure industrial intermediate (1R)-cis-hemicaronaldehydic acid (or biocartol) are convenient synthons for the preparation of a series of chiroporphyrins by condensation with pyrrole. These chiral meso-tetracyclopropylporphyrin