𝔖 Bobbio Scriptorium
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Cyclopropyl imine rearrangement: total synthesis of (±)-isoretronecanol and (±)-trachelanthamidine1–3

✍ Scribed by Harold W. Pinnick; Yeong-Ho Chang


Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
179 KB
Volume
20
Category
Article
ISSN
0040-4039

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📜 SIMILAR VOLUMES


Thermal rearrangement of cyclopropyl imi
✍ R.V. Stevens; M.C. Ellis 📂 Article 📅 1967 🏛 Elsevier Science 🌐 French ⚖ 165 KB

We were impressed by the fact that such structurally dissimilar alkaloid families as the Strychnos, Aspidosperma, Senecio, Amaryllidaceae, and Tobacco all incorporate various perturbations of the pyrrolidine ring system [3]. Reasoning that any potentially general synthetic adventure into this vast a

Stereospecific 1,2-rearrangement of cycl
✍ Masato Shimazaki; Hisaaki Hara; Keisuke Suzuki 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 294 KB

Stereospecific 1,2-rearrangement of cyclopropyl group is described as an efficient route to stereo-defined a-cyclopropyl ketones and cr-cyclopropyl aldols. Acceleration of the reaction by the introduction of trimethylsilyl (TMS) group to the a-position of cyclopropyl group is also noted. ## Cyclop