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Cyclopentenyl sulphides via (3+2)cycloaddition

โœ Scribed by Brian D Gray; Catherine M McMillan; J.Allen Miller; G.Mustafa Ullah

Book ID
104227445
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
199 KB
Volume
28
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Mono-, bi-, and tricyclic cyclopentenyl sulphides, -(1) and (21, are available by zinc chloride catalysed (3+2)cycloaddition of ally1 chlorides to 1-alkynyl sulphides.

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Bicyclo[3.2.1]oct-6-enes via (3+2)cycloaddition
โœ Brian D. Gray; Catherine M. McMillan; J.Allen Miller; Michael Moore ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 210 KB

3+2)Cycloaddition of alkynes to ally1 cations, generated from 3-chlorocyclohexenes and zinc chloride, provides a simple and direct route to bicyclo[3.2.l]oct-6-enes. Bicyclo[3.2.l]octane derivatives are of interest because of their occurrence in natural product structures , many of which are of biol