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Cyclopentenone Derivatives, X. An Easy Approach to Bicyclo[6.3.0]undecane Derivatives

✍ Scribed by Bertram, Heinz-Jürgen ;Jansen, Martin ;Peters, Karl ;Meier, Andreas ;Winterfeldt, Ekkehard


Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
427 KB
Volume
1986
Category
Article
ISSN
0947-3440

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✦ Synopsis


A straightforward route to functionalized bicyclo[6.3.0]undecane derivatives, which can be used in terpene synthesis, is described. The trans configuration of the acetall2 is established by an X-ray structural analysis.

Cyelopentenon-Derivate, XI

). -Ein einfaeher Zugang zu Bieyelo[6.3.0]undeean-Derivaten Es wird ein einfacher Weg zu funktionalisierten Bicyclo[6.3.0]undecan-Derivaten beschrieben, die als Zwischenprodukte bei Terpensynthesen genutzt werden konnen. Die trans- Konfiguration des Acetals 12 wird durch eine Rontgenstrukturanalyse bewiesen. *) All compounds prepared are racemates. For the sake of simplicity only one relative configuration is given in the Schemes.


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