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Cyclopentadienyl Zincates: Synthesis and X-ray Studies of Sodium and Potassium Salts of the [Zn(C5H5)3]− and [Zn2(C5H5)5]− Ions

✍ Scribed by Eleuterio Alvarez; Abdessamad Grirrane; Irene Resa; Diego del Río; Amor Rodríguez; Ernesto Carmona

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
139 KB
Volume
46
Category
Article
ISSN
0044-8249

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✍ Helmut Sitzmann; Thomas Dezember; Oliver Schmitt; Frank Weber; Gotthelf Wolmersh 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 119 KB

Octaisopropylmetallocenes of the lanthanoids Sm (1-Sm), Eu (1-Eu), and Yb (1-Yb) can be obtained easily from the diiodides of the rare earth elements. Like the hexa-(tert.-butyl)metallocenes 2-Sm, 2-Eu, and 2-Yb, they show no tendency towards coordination of donor solvent molecules or alkali salts.