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Cyclopentadienyl-Free Rare-Earth Metal Amides [{(CH2SiMe2){(2,6-iPr2C6H3)N}2}Ln{N(SiMe3)2}(THF)] as Highly Efficient Versatile Catalysts for C–C and C–N Bond Formation

✍ Scribed by Yunjun Wu; Shaowu Wang; Lijun Zhang; Gaosheng Yang; Xiancui Zhu; Zhihong Zhou; Hong Zhu; Shihong Wu

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
727 KB
Volume
2010
Category
Article
ISSN
1434-193X

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## Abstract The potassium salt K(C~5~H~5~BMe) (8) can be obtained from 2‐(Me~3~Sn)C~5~H~5~BMe (7)/KO__t__Bu in toluene in essentially quantitative yield. Metalation of 1‐(dimethylamino)‐3‐methylene‐1,2,3,6‐tetrahydroborinine (9) with MN(SiMe~3~)~2~ (M = Na, K) in toluene afforded the unsolvated sal