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Cyclopentadienyl and pentamethylcyclopentadienyl ruthenium complexes as catalysts for the total deoxygenation of 1,2-hexanediol and glycerol

✍ Scribed by Thibault, Michelle E.; DiMondo, Domenico V.; Jennings, Michael; Abdelnur, Patrícia Verardi; Eberlin, Marcos N.; Schlaf, Marcel

Book ID
111880371
Publisher
Royal Society of Chemistry
Year
2011
Tongue
English
Weight
367 KB
Volume
13
Category
Article
ISSN
1463-9262

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Cyclopentadienyl RuII Complexes as Highl
Cyclopentadienyl RuII Complexes as Highly Efficient Catalysts for the N-Methylation of Alkylamines by Methanol
✍ Alessandro Del Zotto; Walter Baratta; Mauro Sandri; Giancarlo Verardo; Pierluigi 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 162 KB

## Abstract The ruthenium(II) half‐sandwich complex [RuCl(η^5^‐C~5~H~5~)(PPh~3~)~2~] (1) catalyses the reaction between methanol and alkylamines RNH~2~ or R^1^R^2^NH to afford RN(CH~3~)~2~ and R^1^R^2^NCH~3~ products, respectively. The reaction is quantitative and generally fast, at the methanol re