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Cyclopentadienyl RuII Complexes as Highly Efficient Catalysts for the N-Methylation of Alkylamines by Methanol.

✍ Scribed by Alessandro Del Zotto; Walter Baratta; Mauro Sandri; Giancarlo Verardo; Pierluigi Rigo

Publisher
John Wiley and Sons
Year
2004
Weight
149 KB
Volume
35
Category
Article
ISSN
0931-7597

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Cyclopentadienyl RuII Complexes as Highl
Cyclopentadienyl RuII Complexes as Highly Efficient Catalysts for the N-Methylation of Alkylamines by Methanol
✍ Alessandro Del Zotto; Walter Baratta; Mauro Sandri; Giancarlo Verardo; Pierluigi 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 162 KB

## Abstract The ruthenium(II) half‐sandwich complex [RuCl(η^5^‐C~5~H~5~)(PPh~3~)~2~] (1) catalyses the reaction between methanol and alkylamines RNH~2~ or R^1^R^2^NH to afford RN(CH~3~)~2~ and R^1^R^2^NCH~3~ products, respectively. The reaction is quantitative and generally fast, at the methanol re