Cyclopentadienone epoxide: synthesis and photochemistry
โ Scribed by Chapman, Orville L.; Hess, Thomas C.
- Book ID
- 121696258
- Publisher
- American Chemical Society
- Year
- 1979
- Tongue
- English
- Weight
- 361 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
A practical synthesis of cyclopentadienone epoxides 10 and their dimethyl acetals 12 by thermal cycloreversion of appropriate tricyclo~5.2~1.02~6~decenone epoxides is de;cribed. Cyclopentadienone epoxides are elusive structures which have mainly been postulatedastransient intermediates in the photoc
A metal supported [2+2+l]cycloaddition of two cyclic alkynes and one CO group is the key step for the preparation of the first superphanes (1, 2) with a metal-capped cyclopentadienone ring. Cyclic voltammetry reveals a strong interaction between the two ~systems in 2.