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Synthesis and properties of superphanes with cyclopentadienone units

✍ Scribed by Rolf Roers; Frank Rominger; Christoph Braunweiler; Rolf Gleiter

Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 197 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)01744-4

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✦ Synopsis

A metal supported [2+2+l]cycloaddition of two cyclic alkynes and one CO group is the key step for the preparation of the first superphanes (1, 2) with a metal-capped cyclopentadienone ring. Cyclic voltammetry reveals a strong interaction between the two ~systems in 2.

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