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Cyclopalladation of 2-acetylthiophene acetylhydrazone

โœ Scribed by Matsuo Nonoyama


Publisher
Elsevier Science
Year
1978
Weight
119 KB
Volume
14
Category
Article
ISSN
0020-1650

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Synthesis of cyclopalladated acetylhydra
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## Acetylhydrazones of p-methylacetophenone, acetylferrocene, and 2acelylthiophene (HL) are easily cyclopalladated to give the complexes [PdClL] . A palladiumcarbon bond is formed with the ortho positions of phenyl and ferrocenyl rings and with the position 3 of a thienyl ring. The complexes react w

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Cyclometallation is an important method for regioselective activation and functionalization of carbon-hydrogen bonds. Cyclopalladated compounds are useful reagents in organic syntheses ~1-7). We present here our findings on the cyclopalladation and functionalization of 1-(phenylazo)-2-hydroxynaphtha