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Cyclometalated N-Heterocyclic Carbene-Platinum Catalysts for the Enantioselective Cycloisomerization of Nitrogen-Tethered 1,6-Enynes

✍ Scribed by Hélène Jullien; Delphine Brissy; Rémy Sylvain; Pascal Retailleau; Jean-Valère Naubron; Serafino Gladiali; Angela Marinetti


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
561 KB
Volume
353
Category
Article
ISSN
1615-4150

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## Abstract The more electron‐withdrawing the N‐protecting group and the alkene substituent, the slower is the reaction rate of the cycloisomerization of 1,6‐enynes to yield bicyclic products (II) and (IV).